The bartender in the first episode shined. The cowboy and cowgirl bounty announcers from the second episode shine. The acting from the main characters seems a bit forced. If this was pitched as a British futuristic TV show much like Doctor Who or something I would understand. I'm on the third episode and the series still just doesn't seem like it's for me. PS Those sideburns blow me every time.
Update
By ep:6 Vicious his wife & those sideburns blow me every time... but the rest of the Show is actually growing on me